ADVERTISEMENT

Perovskite Solar Cells: A Photovoltaic Technology With Outstanding Light-Harvesting Capabilities Under Indoor Illumination

Perovskite solar cells represent an emerging photovoltaic technology being researched and developed by academic and industrial laboratories worldwide because it is able to bring together at the same time low-cost manufacturing (materials/processes) together with high power conversion efficiencies of the end product.

The vast majority of R&D has focused on the technology operating at standard test conditions (i.e. bright sunlight).

ADVERTISEMENT
Figure schematizing the demonstration of perovskite solar cell technology with outstanding power outputs under indoor lighting for powering electronics in smart buildings, the internet of things, and wireless sensors. Credit:Ā Thomas M. Brown

The Centre for Hybrid and Organic Solar Energy (CHOSE), Department of Electronic Engineering University of Rome ā€“ Tor Vergata, in collaboration with the Department of Physics and Astronomy and London Centre for Nanotechnology at University College London, have developed device architectures with new solution-processed composite electron transport layers that work exceptionally well under artificial indoor lighting (i.e. white LED lamps). Indoor illumination delivers a different spectrum (concentrated in the visible range) and incident power (i.e. 2 to 3 orders of magnitude smaller) compared to that of the sun at standard test conditions. By inserting a thin MgO overlayer over a more conventional SnO2 transport layer, between the perovskite semiconductor film and the bottom transparent electrode, detrimental charge recombination was reduced.

The resulting improvement in the capability of extracting useful electrons by the photovoltaic cell is especially critical at the low illumination levels typically found indoors and has considerable influence on device performance. In fact, the power conversion efficiency improved by 20% and the maximum power density was 20.2 ĀµW/cm2 at 200 lx and 41.6 ĀµW/cm2 at 400 lx (corresponding to a power conversion of 27%) under white LED illumination. To date, these represent the highest output power densities reported for any photovoltaic technology under these typical illumination ranges found in home and office environments.

Ambient indoor conditions represent a milder environment compared to stringent outdoor conditions and are much less demanding on device lifetimes. This, together with their exceptional efficiency under artificial lighting, suggests an initial market for this new photovoltaic technology which is still seeking long-term stability outdoors. Furthermore, all layers of the cells, except for the two electrodes, were solution-processed at low temperatures, making the technology easy to integrate with other printed electronic components on the same substrate, and compatible with low-cost manufacturing. Low-temperature processing means that this technology can be fabricated not only on glass but even on flexible plastic substrate films and thus more-easily integrated with a variety of surfaces and objects.

Figure: perovskite solar cells on glass (left) and plastic film (right). Republished with permission from Springer from: G. Lucarelli, F. Di Giacomo, V. Zardetto, M. Creatore, T. M. Brown, ā€œEfficient light harvesting from flexible perovskite solar cells under indoor white light-emitting diode illuminationā€, Nano Research, 10, 2130 (2017)

There are many objects and low-power devices that need energy to operate, including portable electronics, devices that make buildings/homes ā€œsmart,ā€ and the fast-rising markets of autonomous indoor wireless sensor networks and the internet of things. Having a power source able to efficiently convert energy from indoor lighting, as well as outdoor sunlight, into electrical energy would enable many of these to do without batteries that require periodic replacing and connections to wires. The unparalleled performance demonstrated by these new solar cell architectures can pave the way for perovskite photovoltaics to contribute strongly to energy harvesting and the powering of indoor electronics of the future.

ADVERTISEMENT

These findings are described in the article entitled Highly efficient perovskite solar cells for light harvesting under indoor illumination via solution processed SnO2/MgO composite electron transport layers, recently published in the journal Nano Energy. This work was conducted by Janardan Dagar, Sergio Castro-Hermosa, Giulia Lucarelli and Thomas M. Brown from the Centre for Hybrid and Organic Solar Energy (CHOSE), Department of Electronic Engineering, University of Rome Tor Vergata,Ā and Franco Cacialli from The London Centre for Nanotechnology, University College London.

Comments

READ THIS NEXT

GLY-PRO-GLU Tripeptide Gold Surface Reconstruction Investigated At The Molecular Scale

Biomolecules adsorption at metal surfaces often creates a 2D ordering of the adlayers. The adsorption process can induce in some […]

Molecules In Space: Physics, Chemistry And Biology

The collaboration between spectroscopists and astrophysicists initiated in the 18th century with the purpose of assigning the Fraunhofer lines in […]

Hydropower Pros And Cons

Hydropower has several pros and cons that make it an interesting choice depending on each situation. Some hydropower pros are […]

Some Hints On How To Write And Publish A Good Medical Paper

One of the most noticeable shortcomings of the research career is the general lack of specific training on how to […]

Use Of Blood Or Skin Cells To Model Retinal Diseases In A Dish

AMD (Age-related Macular Degenerescence) is the first cause of visual impairment. The main characteristic of the disease is the occurrence […]

Should You Stop Having Children? The Science, Climate, and Statistics of Population Growth

When the editors of the popular United Kingdom-based publication The Guardian decided to publish an article with the title, “Want […]

Multi-Objective Optimization Of A Solar Driven Trigeneration System

Solar energy exploitation is one of the most promising ways to face major problems as the growing population, the climate […]

Science Trends is a popular source of science news and education around the world. We cover everything from solar power cell technology to climate change to cancer research. We help hundreds of thousands of people every month learn about the world we live in and the latest scientific breakthroughs. Want to know more?