Lamellar Polymer Single Crystal Dielectrics For Electronic Devices

Lamellar polymer single crystals have been studied since the 1950s, while the potential application of these highly-ordered polymers is much less frequently considered. Recently, Professor Hanying Li and Yuhui Yang from Zhejiang University, China, report, for the first time, the electronic application of the lamellar polymer single crystals for the dielectrics of organic field effect transistors (OFETs). The results show that lamellar polymer single crystals are superior to the widely-used polymer films in the sense that much higher charge mobility is achieved.

Transistors are the fundamental building blocks of electronic devices such as displays, sensors, and complementary circuits. Organic materials have been introduced to build OFETs to make low-cost, flexible, and lightweight devices. OFETs are interface devices where charges transport at the semiconductor/dielectric interface, and the properties of this interface significantly determine the device performance of OFETs.

In principle, ordering of the interfacial structure can enhance OFETs performance. Single crystals are ideal candidates for high-performance OFETs due to the ordered molecular packing. As such, single crystals of semiconductors are quite often used for OFETs and high-performance OFETs are achieved. Interestingly, using single crystals in the dielectric side of the semiconductor/dielectric interface is much less frequently considered.

Only in a few cases, were single crystals of mica and organic small molecules used as dielectrics for OFETs by Ueno group (Chem. Lett. 2006, 35, 354-355), Takeya group (Solid-State Electron. 2007, 51, 1338-1343), and Hu group (Adv. Mater. 2011, 23, 5502-5507; Adv. Mater. 2016, 28, 3755-3760). Especially, for the polymer materials that have been widely used as dielectrics in OFETs, the single-crystalline form has not been adopted for OFETs.

  Ultrasmall Nanoplatelets: The Ultimate Tuning Of Optoelectronic Properties

Ideally, a semiconductor/dielectric interface with single-crystalline materials on both sides (i.e., single-crystalline semiconductors and single-crystalline dielectrics) is highly desired to favor the electron transport along the interface. Professor Hanying Li and Yuhui Yang reported this kind of highly ordered interface where Poly(Īµ-caprolactone) (PCL) single crystal was chosen as the dielectric side while 6,13-bis(triisopropylsilylethynyl)-pentacene (TIPS-pentacene) single crystal as the semiconductor side. The fabrication process of OFETs is shown in Figure 1.

Figure 1. Schematic illustrates the fabrication process of OFETs with PCL single crystal as dielectrics and TIPS-pentacene single crystal as semiconductors. PCL single crystals were grown in dilute 1-butanol solution by the self-seeding method, and TIPS-pentacene single crystals were grown via the droplet-pinned crystallization (DPC) method.Ā (Republished with permission fromĀ Polymer)

Obtaining large size and smooth polymer single crystals is the key to the preparation of polymer single crystal dielectrics for OFETs. PCL has been shown to easily form lamellar single crystals with flat crystalline terrace using the self-seeding method but their sizes were too small for OFETs. In order to fabricate OFETs on PCL single crystals, the large size (up to 83 Ī¼m in length) PCL single crystals with a smooth surface were obtained by reducing the nucleus density in the process of crystallization (as shown in Figure 2a-c).

Figure 2. Morphologies and crystalline structures of PCL single crystals and bilayer single crystals. (a) An optical microscopy image of PCL single crystal. (b) An atomic force microscopy (AFM) image of a PCL single crystal. The inset curves show the height profile of the corresponding PCL crystal lamellae. (c) A selected area electron diffraction pattern of a PCL single crystal with the white circles highlighting the diffraction spots, showing the single-crystallinity. (d) An AFM image of bilayer single crystals with TIPS-pentacene ribbons on top of PCL lamellae. (Republished with permission fromĀ Polymer)

Next, crystallization of TIPS-pentacene on the PCL single crystal forms the interface for electron transport in OFETs (as shown in Figure 2d). The devices exhibit hole mobility as high as 4.95 cm2V-1s-1 (average mobility: 1.70Ā±0.97 cm2V-1s-1). The mobility is much higher than that of the devices based on the relatively disordered PCL thin films (average mobility: 0.62Ā±0.24 cm2V-1s-1), indicating the advantage of polymer single crystalline dielectrics. As such, this result demonstrates that single-crystalline polymer dielectrics are promising for high-performance OFET devices.

  How Many Weeks Are In A Year?

These findings are described in the article entitled Polymer Single Crystal Dielectrics for Organic Field-Effect Transistors, recently published in the journal Polymer. This work was led by Hanying Li, Yuhui Yang, and Hongzheng Chen from Zhejiang University.

Speak Your Mind!


Atmospheric Phenomena STEVE Not An Aurora, Instead Another Mysterious Event

In July of last year, there was a thin trail of purple light that was witnessed streaking across the sky […]

Moroccan Miocene Lakes ā€“ New Insights From Stable Isotopes And Sedimentary Analysis

The High Atlas Mountains are the highest mountains in North Africa, running from the Atlantic coast in Morocco to the […]

Handle With Care: Research To Improve Bycatch Survival Through Better Handling

Published by Katrina Cook and Maryann Watson Department of Forest Sciences and Conservation Sciences, University of British Columbia, and Marine […]

100 Fun Trivia Questions For Kids

Check out these fun trivia questions for your kids, especially since summer is the time of year when children have […]

How Tibetan Plateau Pika Use Behavior And Physiology To Respond To A Changing Environment

Published by Qu Jiapeng Northwest Institute of Plateau Biology, Chinese Academy of Sciences and Qinghai Provincial Key Laboratory of Restoration […]

Antidepressant Discontinuation Syndrome

Depression is a highly prevalent, severely debilitating mental disorder that affects nearly 5% of the global population, and has a […]

Analyzing Growth Response To Climate Change In Two Threatened South American Biomes

Increase in greenhouse gases has causedĀ generalized global warming, mainly from the mid-1970s in the Southern Hemisphere. It is expected that […]