Palladium-catalyzed Deoxygenative Amination Of Phenols
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Chao-Jun Li is the Chair Professor and Director of the Green Chemistry Center at McGill University | McGill · Department of Chemistry.

                       

Palladium-catalyzed Deoxygenative Amination Of Phenols

Arylamines serve as important structural units in pharmaceuticals, pigments and functional materials. They are also versatile intermediates in numerous transformations such as C-halo (the Sandmeyer and Schiemann reactions) or C-N (the Buchwald-Hartwig, the Chan-Lam, and the Ullmann reactions) bond formations. Very recently, N-cyclohexyl anilines have been used as a ligand to promote dehydrogenative transformations, and as an antioxidant in food chemistry. To date, a series of elegant methods for the synthesis of N-cyclohexyl anilines have been developed, which can be...

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